S. J. Balian, T. S. Monteiro
We investigate suppression of various decoherence mechanisms at critical points variously termed optimal working points (OWPs) or clock transitions (CTs) of electron paramagnetic resonance (EPR) transitions in Si-based spin qubits, where the frequency -- field gradient is zero ($df/dB=0$). New experiments by Wolfowicz {\it et al.} [arXiv:1301.6567 (2013)] have demonstrated suppression of both instantaneous diffusion, as well as spin diffusion at these points, yielding orders of magnitude enhancement in coherence times: up to seconds, without extrapolation to zero-duration pulses as was until now necessary. We obtain simple analytical expressions and compare with full numerics, explaining the form of decoherence suppression for bismuth donors in Si (Si:Bi). It is demonstrated that behavior at the OWPs cannot be fully analyzed in terms of the behavior of $df/dB$, especially in the case of spin diffusion, indicating the need for an understanding at the level of the underlying microscopic processes entangling the central spin system and the spin bath.
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http://arxiv.org/abs/1302.1709
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