1302.5234 (Horacio Olivares Pilón)

Quadrupole transitions in the bound rotational-vibrational spectrum of
the deuterium molecular ion    [PDF]

Horacio Olivares Pilón

After the study of the three body molecular system H$_2^+$ ({\it J. Phys. B: At. Mol. Opt. Phys.} {\bf 45} 065101), their isotope, the deuterium molecular ion D$_2^+$ is studied. The three-body Schr\"odinger equation is solved using the Lagrange-mesh method in perimetric coordinates. Energies and wave functions for four vibrational states $v=0-3$ and bound or quasibound states for total orbital momenta from 0 to 56 are calculated. The 1986 fundamental constant $m_d=3670.483014\,m_e$ is used. The obtained energies have an accuracy from about 13 digits for the lowest vibrational state to at least 9 digits for the third vibrational excited state. Quadrupole transition probabilities per time unit between those states over the whole rotational bands were calculated. Extensive results are presented with six significant figures.

View original: http://arxiv.org/abs/1302.5234